High-Flux Solar-Driven Thermochemical Dissociation of CO2 and H2O Using Nonstoichiometric Ceria by William C. Chueh, Christoph Falter, Mandy Abbott, Danien Scipio, Philipp Furler, Sossina M. Haile, and Aldo Steinfeld
In the prototype, sunlight heats a ceria cylinder which breaks down water or carbon dioxide
Abstract:
Because solar energy is available in large excess relative to current rates of energy consumption, effective conversion of this renewable yet intermittent resource into a transportable and dispatchable chemical fuel may ensure the goal of a sustainable energy future. However, low conversion efficiencies, particularly with CO2 reduction, as well as utilization of precious materials have limited the practical generation of solar fuels. By using a solar cavity-receiver reactor, we combined the oxygen uptake and release capacity of cerium oxide and facile catalysis at elevated temperatures to thermochemically dissociate CO2 and H2O, yielding CO and H2, respectively. Stable and rapid generation of fuel was demonstrated over 500 cycles. Solar-to-fuel efficiencies of 0.7 to 0.8% were achieved and shown to be largely limited by the system scale and design rather than by chemistry.
A prototype solar device has been unveiled which mimics plant life, turning the Sun’s energy into fuel. The machine uses the Sun’s rays and a metal oxide called ceria to break down carbon dioxide or water into fuels which can be stored and transported.
Conventional photovoltaic panels must use the electricity they generate in situ, and cannot deliver power at night. Details are published in the journal Science. The prototype, which was devised by researchers in the US and Switzerland, uses a quartz window and cavity to concentrate sunlight into a cylinder lined with cerium oxide, also known as ceria.
Ceria has a natural propensity to exhale oxygen as it heats up and inhale it as it cools down.
If as in the prototype, carbon dioxide and/or water are pumped into the vessel, the ceria will rapidly strip the oxygen from them as it cools, creating hydrogen and/or carbon monoxide. Hydrogen produced could be used to fuel hydrogen fuel cells in cars, for example, while a combination of hydrogen and carbon monoxide can be used to create “syngas” for fuel. It is this harnessing of ceria’s properties in the solar reactor which represents the major breakthrough, say the inventors of the device. They also say the metal is readily available, being the most abundant of the “rare-earth” metals. Methane can be produced using the same machine, they say.
The prototype is grossly inefficient, the fuel created harnessing only between 0.7% and 0.8% of the solar energy taken into the vessel. Most of the energy is lost through heat loss through the reactor’s wall or through the re-radiation of sunlight back through the device’s aperture.
But the researchers are confident that efficiency rates of up to 19% can be achieved through better insulation and smaller apertures. Such efficiency rates, they say, could make for a viable commercial device.
“The chemistry of the material is really well suited to this process,” says Professor Sossina Haile of the California Institute of Technology (Caltech). “This is the first demonstration of doing the full shebang, running it under (light) photons in a reactor.”
It has been suggested that the device mimics plants, which also use carbon dioxide, water and sunlight to create energy as part of the process of photosynthesis. But Professor Haile thinks the analogy is over-simplistic. “Yes, the reactor takes in sunlight, we take in carbon dioxide and water and we produce a chemical compound, so in the most generic sense there are these similarities, but I think that’s pretty much where the analogy ends.”
While cerium is quite abundant in the earth’s crust it is one of the “rare earths” and current production is dominated by China. Cerium oxide, which is used to finish semiconductors and obtained from the rare earth element cerium, rose in price from $ 4.70 per kg on April 20 to 36 U.S. dollars a kilo on Tuesday, October 19. An increase of 665 percent.
The k2p blog 